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Volume 4, Issue 3
Review of Bleach Activators for Environmentally Efficient Bleaching of Textiles

Changhai Xu, David Hinks, Ahmed El-Shafei, Peter Hauser, Min Li, Mary Ankeny & Katelyn Lee

Journal of Fiber Bioengineering & Informatics, 4 (2011), pp. 209-219.

Published online: 2011-04

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  • Abstract
Textile wet processing is the most polluting aspect of textile manufacturing and contributes to the global textile industry's substantial carbon footprint. Textile preparation of cotton typically includes scouring and bleaching at high temperature and high pH. Substantial amounts of wastewater are produced that must be treated prior to being released to receiving fresh water. Recent research in our laboratories has focused on the development and application of compounds that enhance the bleaching process. We have developed novel cationic bleach activators that can be used to bleach cellulosic fabrics and fiber blends at reduced temperature, pH, and time. Results show that after optimization equivalent or improved performance in whiteness, absorbency and strength are possible relative to conventional bleaching methods. One of the most promising bleach activators to date is N-[4-(Triethylammoniomethyl) Benzoyl]-Butyrolactam Chloride (TBBC). TBBC was designed in our group to a) exhibit strong oxidation potential when activated; b) have reasonable hydrolytic stability; and c) be inherently substantive towards cellulosic and other fibers. In this paper, we review the development of bleach activators for textile bleaching, and discuss the opportunities and potential hurdles involved in commercialization of bleach activators for textile wet processing.
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@Article{JFBI-4-209, author = {Changhai Xu, David Hinks, Ahmed El-Shafei, Peter Hauser, Min Li, Mary Ankeny and Katelyn Lee}, title = {Review of Bleach Activators for Environmentally Efficient Bleaching of Textiles}, journal = {Journal of Fiber Bioengineering and Informatics}, year = {2011}, volume = {4}, number = {3}, pages = {209--219}, abstract = {Textile wet processing is the most polluting aspect of textile manufacturing and contributes to the global textile industry's substantial carbon footprint. Textile preparation of cotton typically includes scouring and bleaching at high temperature and high pH. Substantial amounts of wastewater are produced that must be treated prior to being released to receiving fresh water. Recent research in our laboratories has focused on the development and application of compounds that enhance the bleaching process. We have developed novel cationic bleach activators that can be used to bleach cellulosic fabrics and fiber blends at reduced temperature, pH, and time. Results show that after optimization equivalent or improved performance in whiteness, absorbency and strength are possible relative to conventional bleaching methods. One of the most promising bleach activators to date is N-[4-(Triethylammoniomethyl) Benzoyl]-Butyrolactam Chloride (TBBC). TBBC was designed in our group to a) exhibit strong oxidation potential when activated; b) have reasonable hydrolytic stability; and c) be inherently substantive towards cellulosic and other fibers. In this paper, we review the development of bleach activators for textile bleaching, and discuss the opportunities and potential hurdles involved in commercialization of bleach activators for textile wet processing.}, issn = {2617-8699}, doi = {https://doi.org/10.3993/jfbi09201101}, url = {http://global-sci.org/intro/article_detail/jfbi/4917.html} }
TY - JOUR T1 - Review of Bleach Activators for Environmentally Efficient Bleaching of Textiles AU - Changhai Xu, David Hinks, Ahmed El-Shafei, Peter Hauser, Min Li, Mary Ankeny & Katelyn Lee JO - Journal of Fiber Bioengineering and Informatics VL - 3 SP - 209 EP - 219 PY - 2011 DA - 2011/04 SN - 4 DO - http://doi.org/10.3993/jfbi09201101 UR - https://global-sci.org/intro/article_detail/jfbi/4917.html KW - Bleaching KW - Bleach Activator KW - Hydrogen Peroxide KW - Cotton KW - Textile Processing AB - Textile wet processing is the most polluting aspect of textile manufacturing and contributes to the global textile industry's substantial carbon footprint. Textile preparation of cotton typically includes scouring and bleaching at high temperature and high pH. Substantial amounts of wastewater are produced that must be treated prior to being released to receiving fresh water. Recent research in our laboratories has focused on the development and application of compounds that enhance the bleaching process. We have developed novel cationic bleach activators that can be used to bleach cellulosic fabrics and fiber blends at reduced temperature, pH, and time. Results show that after optimization equivalent or improved performance in whiteness, absorbency and strength are possible relative to conventional bleaching methods. One of the most promising bleach activators to date is N-[4-(Triethylammoniomethyl) Benzoyl]-Butyrolactam Chloride (TBBC). TBBC was designed in our group to a) exhibit strong oxidation potential when activated; b) have reasonable hydrolytic stability; and c) be inherently substantive towards cellulosic and other fibers. In this paper, we review the development of bleach activators for textile bleaching, and discuss the opportunities and potential hurdles involved in commercialization of bleach activators for textile wet processing.
Changhai Xu, David Hinks, Ahmed El-Shafei, Peter Hauser, Min Li, Mary Ankeny and Katelyn Lee. (2011). Review of Bleach Activators for Environmentally Efficient Bleaching of Textiles. Journal of Fiber Bioengineering and Informatics. 4 (3). 209-219. doi:10.3993/jfbi09201101
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